Study of argon–oxygen flowing afterglow

Abstract

The reaction kinetics in argon–oxygen flowing afterglow (post-discharge) was studied using NO titration and optical emission spectroscopy. The flowing DC post-discharge in argon–oxygen mixture was created in a quartz tube at the total gas pressure of 1000 Pa and discharge power of 90 W. The O(3P) atom concentration was determined by NO titration at different places along the flow tube. The optical emission spectra were also measured along the flow tube. Argon spectral lines, oxygen lines at 777 nm and 844.6 nm and atmospheric A-band of were identified in the spectra. Rotational temperature of was determined from the oxygen atmospheric A-band and also the outer wall temperature of the flow tube was measured by a thermocouple and by an IR thermometer. A zero-dimensional kinetic model for the reactions in the afterglow was developed. This model allows the time dependencies of particle concentrations and of gas temperature to be calculated. The wall recombination probability for O(3P) atoms and wall deactivation probability for (b ) molecules were determined from the fit of model results to experimental data. Sensitivity analysis was applied for the analysis of kinetic model in order to reveal the most important reactions in the model. The calculated gas temperature increases in the afterglow and then decreases at later afterglow times after reaching the maximum. This behavior is in good agreement with the spatial rotational temperature dependence. A similar trend was also observed at outer wall temperature measurement.