Abstract

The ν 5(SO 4 2−) and ν 5(NO 3 −) vibrations, as observed in the Raman spectrum, were studied for several alcali- and earth-alcali sulfates and nitrates in water solution. For the sulfate solutions also the high frequency Raman band of water was observed. The p.m.r. solvent shift for these solutions and for solutions of CdCl 2, MgCl 2, ZnCl 2, CdBr 2 were also investigated. A discussion is presented of possible correlations between the Raman spectral parameters, the ionic contributions to the p.m.r. shifts and the structure of electrolyte solutions.

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