Abstract
The complete theory corresponding to a CE mechanism when applying cyclic chronopotentiometry to a spherical electrode of any size is developed. The influence of several variables on the transition time ratios, such as the electrode radius, rate constants of the homogeneous chemical reaction and current density, is discussed. A simple and practical criterion based on the variation of current density applied to the electrode is proposed for the detection of a CE mechanism.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
