Study of η 5-(1-chloro-4-methylcyclohexadienyl) and η 5-(1-methyl-4-chlorocyclohexadienyl)tricarbonylmanganese complexes in solution and in the solid state

Abstract

The spectroscopic studies of neutral η 5-(1-chloro-4-methylcyclohexadienyl) and η 5-(1-methyl-4-chlorocyclohexadienyl) tricarbonylmanganese complexes have been realized in solution by 1H NMR spectroscopy as well as in the solid state. The structures showed a dihedral angle of the sp 3 carbon of 33.2° and 36.6° with respect to the cyclohexadienyl ring. To cite this article: F. Rose-Munch et al., C. R. Chimie 6 (2003).