Study and Evaluation of Aging Performance of Petroleum Asphalts and Their Constituents During Oxygen Absorption. I. Oxygen Absorption Behaviors and Kinetics

Abstract

The oxygen absorption behaviors and kinetics of Shanjiasi, Shengli, and Renqiu petroleum asphalts and their constituents including saturates, aromatics, resins, and asphaltenes were successfully studied at 50°C, 0.133 MPa (O2) and 1 mm sample film in darkness by means of precise measurement of oxygen pressure changes in reactor. The experimental results that the resin and the asphaltene can easily absorb oxygen and they are more active constituents in petroleum asphalt, while the saturate hardly absorbs oxygen, which is the most stable constituent of petroleum asphalt. The better the antiaging performance of straight run petroleum asphalt, the more stable its constituents and the less oxygen they absorb generally. The oxygen absorption rate of asphaltene diluted with the lower viscous saturate is obviously higher than that of pure asphaltene. The resin constituent of Shanjiasi asphalt could remarkably improve the antiaging ability of Shengli asphalt by the constituent substitution. The kinetic model of maximum combined oxygen presented in this paper could satisfactorily explain the oxygen absorption behaviors of petroleum asphalts and their constituents, and the oxygen absorption quantities calculated by the model are very identified with the test ones.