Abstract
The syntheses of 6β,7β, 8α, and 6β, 7β, 8β-trihydroxy labdadienes, 2a and 2b respectively, were performed starting from the decalin 3, in order to determine the exact structure of compounds, isolated from plant sources, for which configuration at C-8 was not clearly demonstrated. As a result, the structure 2a was established with certainty for crotomachlin, a diterpine from Croton macrostachys.
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