Abstract

Dipole moments and molar Kerr constants of complexes of phenols with phosphoryl compounds were studied to establish the structure of complexes and parameters characterizing the proton acceptor ability of these compounds. The structures of these complexes and parameters ( μ H, Δ( mk) S, log K and δ 0) were established. It has been suggested that a new parameter Δ( mK) S — structural additive difference of the molar Kerr constant — makes it possible to determine changes of polarity and polarizability of the systems during complex formation.

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