Abstract
AbstractThe ozonides of methyl 9‐octadecenoate, 9‐octadecene and methyl 9‐octadecendioate (along with pelargonyl aldehyde, methyl azelaaldehydate and a fraction which appears to consist mainly of hydroperoxy‐ozonides) were isolated from ozonizations of methyl oleate in pentane and methylene chloride at 蜢65C. The relative amounts of these compounds were determined in ozonizations of methyl oleate in pentane, methylene chloride and ethyl acetate.Present concepts of the mechanism of the reaction are elaborated on the light of new information on the products of the ozonization of methyl oleate and related compounds under various conditions.
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