Abstract

This paper focused on the comparative evaluation of cure characteristics and mechanical properties of blends of natural rubber with dichlorocarbene modified styrene–butadiene rubber and chloroprene rubber with different blend composition. It was found that the Mooney scorch time and cure index shows a negative deviation from the calculated value based on the interpolation between the two component elastomers. However for the blends, modulus and hardness show a positive deviation. The mechanical properties of NR/DCSBR blend are higher than that of NR/CR blends. Flammability, oil and ozone resistance of the blend showed that as the NR content in the blend increases these properties were decreases and also NR/DCSBR blend showed excellent thermal, oil and ozone resistance than that of NR/CR in entire blend ratios. The mechanical properties, modulus and hardness were also investigated after oil immersion. The changes in mechanical properties were correlated with variation in cross-link density estimated from stress–strain and swelling behavior.

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