Abstract
The authors synthesized from isovanillin, salicifoline chloride (I), viz., β-(3-hydroxy-4-methoxyphenyl)-ethyl-trimethylammonium chloride, a main base of Magnolia salicifolia Maxim., Magnolia Kobus DC., and Magnolia stellata Maxim., belonging to the Magnoliaceae, which grow in Japan. Thus, the structure of salicifoline chloride has synthetically been confirmed as being represented by formula (I). In this connection, β-(3-methoxy-4-hydroxyphenyl)-ethyl-trimethylammonium chloride (IV), β-(2-hydroxy-3-methoxyphenyl)-ethyl-trimethylammonium chloride (VI), and β-(2, 3-dimethoxyphenyl)-ethyl-trimethylammonium iodide (VII), having the structure analogous to that of salicifoline chloride, have also been synthesized.
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