Abstract
ABSTRACT The activation of sp 2 - and sp 3 - C–H bonds by η-cyclopentadienyl tungsten derivatives is described. Evidence is presented for the reversible elimination of alpha-hydrogen from a tungsten-methyl system. Molybdena- and tungstena- cyclobutane derivatives have been synthesised and their photoinduced evolution of olefins has been investigated. Rules are given for predicting the selectivity of nucleophilic addition to 18-electron organotransition metal cations containing polyene ligands.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
