Abstract
An amide-based open-chain crown ether ligand and its complexes with europium and terbium were synthesized. The complexes were characterized by elemental analysis, infrared spectra and conductivity. The europium and terbium ions were found to coordinate to the CO oxygen atoms and pyridine nitrogen atoms. The fluorescence properties of these complexes in DMF and CH 3OH/CHCl 3 were studied. Under the excitation of UV light, these complexes exhibit characteristic fluorescence of europium and terbium ions. The solvent factors influencing the fluorescent intensity are discussed.
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More From: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
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