Abstract
AbstractAlkylation of 5‐nitroindazole (I) with dimethyl sulphate and/or diethyl sulphate in presence of sodium hydroxide yields mixtures containing more 2‐alkylated than 1‐alkylated products. The action of diazomethane on 5‐nitro (I) and 6‐nitro‐indazole (IV) was investigated. Reduction of nitroindazoles with hydrogen on Pd/charcoal proceeds smoothly. The synthesis of several new benzimidazole and indazole dye intermediates is also described.
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