Studies on partial compatibility of PP and PS

Abstract

Blends of polystyrene (PS) and polypropylene (PP) were prepared through melt compounding. With an increase of PS content up to 30 wt%, the tensile strength of PP/PS blends increased from 37.4 MPa to 42.2 MPa, although the blends were widely regarded as immiscible. The DSC results showed that there's slight decrease in melting temperature of PP, showing insufficient evidence for partial compatibility between PP and PS. Almost no variation of distinct characterization peaks were observed in FTIR spectra of PS/PP blends compared with those of neat PP and PS, indicating there is no chemical interactions between PP and PS. Since the morphology investigation showed a droplet structure as PS content was up to 30 wt%, the improvement of tensile strength could be simply considered as due to the reinforcing effect of dispersed rigid PS particles on the PP, combining with partial compatibility between them as evaluated by change of C p at glass transition for both PS and PP. More interestingly, DSC and DMA results showed that the blending of PS and PP could lead to a substantial decrease of the glass transition temperature (T g) of PP, and increase of T g of PS. The annealing experiment was carried out to understand the change of T g in PP/PS blends. It is believed that the compressive stress generated by the contracting PP should be the dominant mechanism for the T g elevation of PS. On the other hand, the T g decrease of PP is likely owing to the creation of a large amount free interface of PP and the dilatation of the PP phase resulting from the corresponding tension exerted by PS during cooling.