Abstract
Reaction of 1-phenylsulfonul-3,3,3-trifluoropropene(1) with carbonyl-stabilized enolate anions smoothly proceeded to give the addition products(7) in good yield while with an alkyl-lithium or Grignard reagent the formation of the vinyl anion(8) was one of the reaction pathways. Reaction of 1 with the chiral nucleophiles(11, 16) was carried out to give the functionalized trifluoromethylated compounds(13, 7b) in 4-43% ee
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