Abstract
The reactions of the novel NADH model compounds 2 with methyl benzoylformate and some other ketonic compounds were studied. The 3-( p-tolylsulfinyl) derivaties 2 successfully reduced methyl bezoylformate to give methyl ( R)-mandelate in good chemical and optical yields. Some other ketones were also found to be reduced with the compound 2b. A possible transition state model is discussed.
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