Abstract

An effectiveness of tetraallyl titanate as a flame retarding agent was investigated. The monomer of tetraallyl titanate was synthesized from esterification of titanium tetrachloride or by interesterification of ethyl titanate, and it was found that the product obtained by the latter method had higher purity and gave better yield. The polymer could be prepared easily by use of t-butylhydroperoxide, but the homopolymer was very brittle and could not be applied for practical use, while copolymerization with methacrylate gave hard resin. No flame retarding effect was shown by a single use of tetraallyl titanate but its effect was increased by a combined use with other flame retarding agent.

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