Abstract

AbstractIn this work, the effect of the catalyst content was investigated in terms of the thermal and mechanical properties of epoxy resins at elevated temperature. A synthesized cationic latent thermal catalyst, N‐benzylpyrazinium hexafluoroantimonate (BPH), was used to cure epoxy resins. The content of catalyst added was 0.5, 1, 2, 3 and 5 wt% and the heating time was varied from 0 to 1024 h. As a result, the mechanical properties, including flexural strength, elastic modulus in flexure and impact strength, as well as thermal‐oxidative resistance, showed a maximum value in the presence of 1 wt% BPH. With increasing elapsed time, up to 4 h, the thermal and mechanical properties of the specimens were improved. These results show that the internal structure of the epoxy system was stabilized, and post‐curing for a longer period of time, resulted in improved thermal and mechanical behaviour of the cast specimens. Copyright © 2004 Society of Chemical Industry

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