Studies on dielectric properties of Al–Zr oxide composites sintered by thermal plasma

Abstract

High-density sintered product of Al x –Zr 100− x ( x=0, 10, 20,…100) composites were produced using low-cost extended arc thermal Plasma heating (EATPH) source. Dielectric properties of these samples were studied as a function of different frequencies and at different temperatures. Particle sizes and density of the plasma-sintered products were controlled by controlling the plasma power, sintering time and plasmagen gas flow rate during sintering. Morphology and structure of sintered Al–Zr samples were examined by SEM and X-ray diffraction (XRD) to understand the plasma-sintered induced dielectric properties. It is noted that frequency- and temperature-dependent dielectric constant and loss factors are the consequence of polarization of dipole moment, which varied with the variation of plasma-sintered particle size. It is also observed that surface charge polarization along with dipole screening play crucial role at higher frequencies and at higher temperature. Dipole pinning and depinning mechanism are proposed to explain this complicated dielectric behavior.