Studies of water quality in the Ouro Preto region, Minas Gerais, Brazil: the release of arsenic to the hydrological system

Abstract

Ouro Preto county is south-east of Quadrilatero Ferrifero in the state of Minas Gerais, one of the most known Brazilian mining regions, producing gold, topaz gems and several kinds of iron and manganese ores. However, these activities are the main forms of environmental degradation, affecting the surface and groundwater which is used for public supply and are the source of heavy metal contamination, including mercury and arsenic. The mining and predatory prospecting activity (garimpos) has been carried out in Minas Gerais since the seventeenth century. At that time, hundreds of placer gold deposits were discovered on the streams in the region of Ouro Preto and Mariana, causing the first big gold rush in Brazilian history. This work presents public supply water quality data from a seasonal cycle, from September 1999 (winter) to February 2000 (summer). Chemical and physical-chemical parameters were assessed with the content of heavy metals. Leaching tests with rock samples to assess contribution to the metal content of water were carried out. Elements in the rocks have been determined and water analysis allowed the hydrogeochemical classification of water. Leaching tests demonstrate the oxidizing conditions under which the As (and the other elements) is being mobilised to the hydrological system. As and Fe are elements dispersed in the drainage of the regions. This is due to the high amounts of sulfide and to the iron formations of the region.