Abstract

The fine structures of the products of the cleavage of the heterorings of chromones and 4-pyrones by ammonia and primary and secondary amines, i.e., 2-β-aminoacrylylphenols (I) and di(β-aminovinyl) ketones (II), were studied by means of IR and PMR spectra, and it was established that I and II, which contain amino groups with a hydrogen atom attached to the nitrogen, exist in the cis form with double intramolecular (chelate) bonding between one carbonyl and two proton-containing groups.

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