Abstract

The kinetics of the process of using phosphorus-containing mineral compounds by their decomposition, which are actual problems, has been studied. At beginning of the it have been notified that the process takes place in two stages. These stages of the process are differed from each another mainly by rate of process realization, because a rate of the first stage is much more that a rate of the second stage. This fact is a reason of the deep research of kinetic of given process. Apart from that a detailed study of these processes connect with some problems of enter prices. All these question are analizied in the work, also the information by methodical carry out of experiments. Regime parameters correlation of components, concentrations of components, a time requite for realization of process are presented. The dependence of degree by different mass correlation of components from the time realization of process are also shown. In the work the types existence of precipitate, monitite brush it are shown. On base of received date a dissolubility of the base received product are graphically presented. In the work an influence of mass correlation of CaO?P2O5 and time of process realization on precipitation is studied. It have been determined that by 650C temperature a mass correlation of the base components must be equal to one, by that a time being used on neutralization process don’t play the practical role, because its increase and decrease don’t influence practically on process indices. The results shown that by equality of components CO?P2O5=1 correlation during four hours the precipitation degree makes up to 90,66 % and during 1 hour this index is 78,2 % for duringthe remaining three during this index is increased on 12 %. By using of these received data these is a possibility determination of the optimum technological conditions for given process. it is shown that there are opportunities to achieve processivization, to increase the use of raw materials and to obtain an environmentally friendly product with the introduction of regime parameters and component ratios in the absolute state.

Highlights

  • Исследования процесса разложения фосфоросодержащих минеральных соединений серной кислотой для различных целей показали, что процесс разложения происходит в основном в две стадии

  • The results shown that by equality of components CO∕P2O5=1 correlation during four hours the precipitation degree makes up to 90,66 % and during 1 hour this index is 78,2 % for duringthe remaining three during this index is increased on 12 %

  • При этом не требуется складское дозревание камерного продукта для использования или грануляции

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Summary

Introduction

Исследования процесса разложения фосфоросодержащих минеральных соединений серной кислотой для различных целей показали, что процесс разложения происходит в основном в две стадии. Для цитирования Ганбаров М.Б., Атаев М.Ш., Газвини К.А. Исследования преципитирования в ходе процесса разложения фосфоросодержащих соединений // Вестник ВГУИТ. For citation Ganbarov M.B., Ataev M.Sh., Gazvini K.A. Studies of precipitation during the decomposition process of phosphorus-containing compounds. В реакторе-нейтрализаторе при 65 °C на пульпу суперфосфата добавляется определенное количество суспензии ракушечника и проводится нейтрализация фосфорной кислоты в соотношении СаО/Р2О5 = 1,0 в течение 60 мин.

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