Abstract
Selectivity in reductive elimination of ethane and RMe has been observed for benzyl and phenacyl complexes Me 2RPd(L 2)Br (L 2 = bipy, phen), with product ratios dependent upon R and L 2, and cationic intermediates detected by 1H NMR spectroscopy for oxidative addition of CD 3I and phenacyl bromides to Me 2Pd(L 2). The crystal structure of fac-Me 2( p-BrC 6H 4CH 2)Pd(phen)Br has been determined.
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