Studies of nano-SiO2 and subsequent water curing on enhancing the frost resistance of autoclaved PHC pipe pile concrete

Abstract

Autoclave curing will cause severe deterioration on the frost resistance of pre-stressed high-strength concrete (PHC) pipe pile. To clarify the frost resistance degradation mechanism of autoclaved PHC pipe pile concrete and obtain effective improvement measures, nano-SiO2 (NS) with cement replacement ratios of 0.5%, 1.0%, and 1.5% were adopted, and concrete specimens were fabricated and subjected to standard curing, autoclave curing, and autoclave curing + one week of subsequent water curing, respectively. Then, a rapid freeze-thaw cycle experiment was utilized to test their frost resistance. In addition, the micro-morphology and pore structure of different concrete were studied through scanning electron microscopy and nuclear magnetic resonance. The results indicate that the mechanisms of the degradation of autoclaved concrete in frost resistance are the increase of concrete porosity, harmful pore ratio, and concrete brittleness. Compared with standard curing, autoclave curing can result in 68.5% loss in the frost resistance of concrete. Through playing the filling and pozzolanic effects, NS can improve the compactness of autoclaved concrete and increase its frost resistance to a certain extent. Subsequent water curing can replenish water into concrete, promote the hydration of the residual unhydrated cementitious materials in concrete, enhance the compactness of concrete, and play a positive role in improving the frost resistance of concrete. The incorporation of 1.0% NS can enhance the frost resistance of autoclaved concrete by 66.6%, while the combination of 1.0% NS incorporation and one-week subsequent water curing can enhance the frost resistance by 89.2%. Exponential function can be used to simulate the frost resistance degradation of the autoclaved PHC pipe pile and predict its service life based on frost resistance.