Abstract

An experimental method for studying ion recombination processes using pulse radiolysis is described. The electron-ion recombination coefficient in N2 (280–980 torr) has been determined to be 3± 0.6× 10−6cm3ion−1·sec−1 at 25°C by analysis of the light emitted by N2(C 3πu), which is produced in the neutralization reaction. This recombination coefficient obeys a T−1/2 dependence. The formation of O3 from an O2–SF6 system was used as a radiation dosimeter to obtain the concentration of ions produced by a pulse of 13 MeV electrons.

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