Studies of heterogeneous catalysis using high-resolution solid state NMR

Abstract

Recent results obtained at the institute of Catalysis from studies of heterogeneous catalysis using high-resolution1H,13C,15N,27Al,29Si,31P and51V solid state NMR have been summarized. Emphasis is made on: (1) structural studies of active in catalysis compounds and sites in supported oxides, hydrides and inorganic acids; (2) studies of structures and properties of surface OH groups active in Bronsted acid catalysis; (3) studies of Lewis acidity of heterogeneous catalysts using15N NMR of adsorbed N2O and (4) studies of adsorption mechanisms for molecules of reactants over various catalysts.