Abstract
Acetolysis of 8-bromoneoisolongifolene generates, besides two normal products (of elimination and S N2 displacement), which were minor, one rearranged elimination product and a tertiary acetate. The rearranged diolefine arises from acetic acid-catalysed rearrangement of the normal elimination product, while the tertiary acetate is a Wagner substitution product arising from a syn-migration. In this context various factors controlling such migrations are discussed and, the possible role of energetics of the incipient carbonium ion at the migration origin highlighted.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
