Abstract
The experimental determination of the effect of ohmic overpotential on the transient response of a three-dimensional progressive nucleation and growth mechanism is described. Experimental data are shown to agree with theoretical predictions. Corrected data are considered in terms of the growth of spirals at the electrode/electrolyte interface. The rate constant for lattice growth perpendicular to the electrode surface is shown to have a Tafel-type dependence on overpotential.
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