Structuring and viscoelastic properties of polyurethanes, doped with aerosil nanoparticles and activated by xanthene dyes

Abstract

Effects of xanthene dyes and aerosil nanoparticles on the structure and dynamic characteristics of the cross-linked polyurethane were investigated by the IR-spectroscopy, dynamic-mechanical analysis, and electronic paramagnetic resonance methods. Dye molecule presence causes self-association of urethane groups within polymer rigid segments, weaker interactions between urethane groups and flexible oligoether parts and increased oligoether mobility. Increased mobility of flexible segments by xanthene dyes provides the necessary beam strength due to compensating the nanofiller network effect. The most efficient polyurethane material in the radiation resistance is expected to be a polymer composite with the highest permeability and the lowest modulus of elasticity.