Abstract

The structures of molten CuCl, CuBr and CuI have been measured at two temperatures, using the neutron diffraction. The structure factors of molten CuI and CuBr show a distinct prepeak at about 0.9 Å -1 . These peaks may be caused by a kind of chemical ordering effect. The information of partial structures are estimated from the total pair distribution functions and the total radial distribution functions using the Davidon-Fletcher-Powell method. In molten CuCl, the first peak positions of the partial distribution functions agreed with those obtained by the isotope enrichment method.

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