Abstract
Gas-phase sulphur hexafluoride is a regular octahedron with an S—F bond length ( r g) of 1.561(2) Å and mean amplitudes of vibration of 0.044(1) Å for S—F, 0.056(6) Å for F-F trans and 0.061(2) Å for F—F cis . Uncertainties correspond to 3σ.
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