Abstract
The synthesis, structure, and phosphorescence properties of two families of triphosphine-supported Au(I)–Ag(I) heteronuclear alkynyl cluster complexes with unprecedented Au2Ag2 and Au8Ag4 cluster structures are described. The phosphorescence emission over the whole visible light region was systematically tuned through modification of the electronic effects in aromatic acetylide ligands to attain bright phosphorescence with different luminescent colors. Introduction of electron-withdrawing CF3 to phenylacetylides results in the emission spectral blue-shift, while it shows progressive red-shift upon introducing electron-donating But, OMe, or NMe2. As demonstrated from both experimental and theoretical studies, the phosphorescence arises primarily from 3LLCT/3IL and Au2Ag2/Au8Ag4 cluster-centered 3[d→p] transitions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
