Abstract

Abstract Reactions of NiCl2·6H2O and Ni(CH3COO)2·4H2O with tridentate ligand yielded di- and trinuclear nickel(II) complexes of [Ni2(HL1)2Cl2(MeOH)2] (1) and [Ni3(HL2)2(CH3COO)4(MeOH)2] (2) (H2L1 = N-(2-hydroxybenzyl)ethanolamine), H2L2 = N-(2-hydroxybenzyl)propanolamine), respectively; the magnetic susceptibility measurements revealed that 1 and 2 have singlet and septet spin ground states, respectively.

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