Structures and electrical properties of molecular conductors based on bis-fused TTF donors with bis(alkylthio) groups

Abstract

Abstract Several bis(alkyldithio) derivatives of BDT-TTP (BTC n -TTP), where BDT-TTP is 2,5-bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene, have been synthesized. Cyclic voltammograms of new donors consist of four pairs of single-electron transfer waves, and the first redox potentials ( E 1 ) are higher by 0.04–0.05 V than that of unsubstituted BDT-TTP. The TaF 6 - salt of bis(methylthio) derivative (BTM-TTP) have the so-called β-type array of the donors. A tight-binding band calculation of (BTM-TTP) 2 TaF 6 suggests that this salt has a quasi one-dimensional Fermi surface. The BTM-TTP salts with the PF 6 - and TaF 6 - anions exhibit metallic temperature dependence down to 90 K, while the SbF 6 - salt is a semiconductor with the activation energy of 0.13 eV.