Structured electroplating sludge derived membrane for one-step removal of oil, metal ions, and anions from oil/water emulsions

Abstract

The effective simultaneous treatment of hazardous waste sludge and complex oil/water emulsions in one way is urgently desired but still a challenging issue. Herein, this work for the first time presents a green and efficient strategy to fabricate an electroplating sludge (ES) derived multifunctional self-supporting membrane for the one-step removal of emulsified oils, soluble metal ions, and anions in complex oily wastewater. Due to low cost of ES and sustainability of the solvent selected in fabrication process, the large-scale application of the membrane is easily to promote. The assembled hierarchical nanostructure endowed robust underwater superoleophobicity of the membrane even under various corrosive aqueous environments, as well as excellent ultra-low oil adhesion and anti-oil-fouling performance, without chemical modification. Significantly, the multifunctional membrane possessed desirable simultaneous separation efficiency for five typical oil-in-water emulsions (>99.4%, high oil/water selective wettability), including crude oil-in-water emulsion with high viscosity (>99.6%), Cu2+ (>96.1%, surface complexation and ionic exchange), and Cl- (>92.7%, electrostatic attraction). Therefore, this green, low-cost, and multifunctional membrane not only allows the large-scale resource utilization of hazardous waste sludge, but also effectively solves the problems of complex oily wastewater purification.