Abstract
We have comparatively studied adsorption and decomposition of NO on Au(997) and Au(110)-(1×2) surfaces by means of TDS, XPS, and DFT theoretical calculation. The lowest-coordinated Au atoms on both surfaces are 7-coordinated, but the surface chemistry of NO differs very much on these two surfaces. An α-NO species dominates on the Au(997) surface, while besides the similar α-NO species, another less stable and more abundant β-NO species also appear on the Au(110)-(1×2) surface. Part of α-NO species decomposes into O adatom and N2O upon heating, but the less stable β-NO species exhibits a much higher decomposition reactivity than α-NO species and facilely decomposes into O adatom and N2O on the Au(110)-(1×2) surface during the NO exposure at 105K. The accompanying DFT theoretical calculation results demonstrate that chemisorbed (NO)2 dimer species dominate the surface chemistry of NO on the Au surfaces. α-NO species is the most stable (NO)2 dimer species that chemisorbs on the 7-coordinated ridge Au atoms of both Au(997) and Au(110)-(1×2) surfaces via the N atoms and exhibits a high activation barrier for the decomposition reaction. β-NO species corresponds to less stable (NO)2 dimer species that chemisorbs on the trench Au atoms of the Au(110)-(1×2) surface via both N and O atoms and exhibits a low activation barrier for the decomposition reaction. These comprehensive experimental and theoretical calculation results reveal at the molecular level the origin of structure sensitivity and low-temperature catalytic activity of supported Au nanocatalysts in NO decomposition reaction.
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