Abstract

The mononuclear complex [Fe(SC2H3N3)(SC2H2N3)(NO)2]·0.5H2O 1 of the ‘g = 2.03 family’ with protonated and deprotonated ligands, which provide a neutral structure and are connected via the sulfur atom in a monodentate way, has been synthesised and characterised by X-ray diffraction, IR, EPR and Mössbauer spectroscopy

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