Abstract

The complex formation in the K2PdCl4-nitrilotrimethylenephosphonic acid (NTMP) system with a metal to ligand molar ratio of 1: 1 and 1: 2 was studied by 31P and 1H NMR spectroscopy. The formation of equimolar complexes with NTMP coordinated in the bidentate ([N,O]) and tridentate ([N,O,O]) fashions depending on the reactant and chloride ion concentrations and solution pH was observed.

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