Structure of nanocrystalline ammonothermal GaN in dependence of temperature and type of acidic mineralizer

Abstract

This study investigated ammonothermal synthesis of nanocrystalline gallium nitride (GaN) in supercritical ammonia with acidic mineralizers NH 4X (X=Cl, Br, I) at 400–500 °C. Results showed that three types of acidic mineralizers could effectively accelerate the formation of GaN. The mixed hexagonal/cubic phase fractions and lattice parameters of nanocrystalline GaN were calculated by the Rietveld refinement method. SEM showed an agglomerate of nanocrystalline GaN. A considerable amount of GaN was synthesized using NH 4Cl as the mineralizer, however, there was no yield using NH 4Br or NH 4I at 400 °C. For acidic mineralizers, both hexagonal structures (wurtzite) and cubic structures (zincblende) were obtained in ammonothermal synthesis by XRD and Raman measurement. GaN synthesized with NH 4Br and NH 4I showed mixed phases of hexagonal-GaN (h-GaN) and cubic-GaN (c-GaN) at 450–500 °C. In the case of NH 4Cl mineralizer, GaN only exhibited mixed phases of h-GaN and c-GaN at 500 °C, but pure h-GaN at 400–450 °C. Based on the results, NH 4Cl favored pure h-GaN, and NH 4Br and NH 4I favored c-GaN at 400–450 °C.