Abstract

There are two independent similar copper(II) complexes in the asymmetric unit. The coordination about copper(II) in each complex forms a distorted square pyramid with the tetraamine N atoms equatorial and the N atom of the isothiocyanato group axial. The two five-membered rings are in skew forms and the two six-membered rings in chair forms. The isothiocyanato groups are almost linear. Hydrogen bonds help stabilize the crystal structure

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