Structure of Hexafluorostannate Ion [SnF6]2–: the 119Sn and 19F NMR MAS-Spectroscopic Studies and Ab Initio Calculations

S P Gabuda,S G Kozlova,V V Tverskikh,V Ya Kavun

doi:10.1023/a:1021826513857

Structure of Hexafluorostannate Ion [SnF6]2–: the 119Sn and 19F NMR MAS-Spectroscopic Studies and Ab Initio Calculations

S P Gabuda, S G Kozlova + Show 2 more

https://doi.org/10.1023/a:1021826513857

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Journal: Russian Journal of Coordination Chemistry	Publication Date: Jan 1, 2003
Citations: 6

Affiliation: Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, Boreskov Institute of Catalysis

#19F NMR Chemical Shifts #119Sn NMR Chemical Shifts + Show 8 more

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Abstract

The 119Sn and 19F NMR chemical shifts in alkali-metal hexafluorostannates are measured. Data of MAS-spectroscopy and ab initio calculations reveal that [SnF6]2– has a distorted structure due to intramolecular electron correlation interactions in this anion.

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