Abstract
Abstract X-ray diffraction was done with molten Fe66,7 Si33,3 and molten Fe33,3 Si66,7 . The coordination numbers versus the concentration lie above the connection line between the coordination numbers of the unalloyed molten elements Fe and Si, respectively, which means a tendency for microsegregation. The pair correlation function of molten Fe66,7 Si33,3 was modeled using the data of crystalline Fe2 Si. At the same time, the pair correlation function of the molten alloy Fe33,3 Si66,7 can be modeled using the data of the corresponding crystalline alloy. Thus for molten Fe33,3 Si66,7 microsegregation into FeSi2 and Si or FeSi and for molten Fe66,7 Si33,3 microsegregation into Fe2 Si and Fe or FeSi exists.
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