Abstract

The structure of hydroxylated alumina surface is analysed by IR spectroscopy. The variety of OH groups differing in number and coordination of surrounding metal atoms, for the completely hydrated surface, either formed by ideal low-index planes, or complicated by crystal edges and corners or cation vacancies, is restricted to six, but grows dramatically upon dehydroxylation. The results account for the complex structure observed previously in the IR spectra of surface OH groups after high-temperature treatment, and enable us to explain specific properties of transition aluminas.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.