Abstract
A novel nitrido technetium complex was synthesized by the reaction of the KYCAR (lysyl-tyrosyl-cystyl-alanyl-arginine) ligand with [(n-C4H9)4N][99TcNCl4]. The structure of the complex was analyzed by 1H- and 13C-NMR and IR spectroscopy as well as by elemental analysis. The nitrido technetium complex with KYCAR has a square pyramidal structure in which two KYCARs coordinate to the Tc atom through both an N and a deprotonated S atom of cysteine. The complex possesses a trans configuration.
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Schedule a callMore From: Journal of Radioanalytical and Nuclear Chemistry Letters
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