Abstract
Synthesis, crystal structure, and photoluminescence studies of a one dimensional silver coordination polymer {[Ag(L1)(CH3CN)][Ag(L1)(OTf)](OTf)}n (1) comprising of Ag(I) and a new flexible organic linker bis(pyridine-3-ylmethyl)terephthalate (L1) exhibiting closed-shell d10⋯d10 argentophilic interaction, is reported. The compound 1 consists of two kinds of (double and single stranded) 1D coordination polymeric chains running parallel and displaying short Ag(I)⋯Ag(I) distances. Notably, the coordinated triflate anion, μ2-bridging mode of acetonitrile and stacking interactions play an important role in the realization of 1D quadruple metal–organic chain in compound 1. Treatment of silver triflate with isomeric ligand, bis(pyridine-2-ylmethyl)terephthalate (L2) resulted in a polymorph of previously reported 1D zigzag coordination polymer {[Ag(L2)](OTf)(H2O)}n (2). Both organic ligands and Ag coordination polymers are characterized by various analytical techniques. Crystal and molecular structures of the isomeric ligands (L1, L2) and their Ag(I) coordination polymeric architectures (1, 2) are correlated with their photoluminescence properties.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
