Structure, IR spectra and dielectric properties of Bi 2O 3–ZnO–SnO 2–Nb 2O 5 quarternary pyrochlore

Abstract

A new series of pyrochlore compounds (Bi 1.5Zn 0.5)(Zn 0.5− x/3 Sn x Nb 1.5−2 x/3 )O 7 (0⩽ x⩽1.5) have been prepared by the solid reaction technique. X-ray diffraction (XRD) and IR absorption spectra were used for analyzing the compositions. Single-phase specimens having cubic pyrochlore structure were obtained for various Sn content. Only one broad band ascribable to B–O stretching vibration was observed for each sample. The dielectric properties were systematically studied and the temperature dependence of the dielectric constant and dielectric loss was measured in the temperature range 150–200 °C. At room temperature (RT), the dielectric constant for Sn-doping Bi-based ceramics decreased and the temperature coefficient increased with increasing Sn 4+ content. Rather low dielectric loss was obtained for series compositions.