Abstract

A series of tertiary amines have been screened for their function as switchable polarity solvents (SPS). The relative ratios of tertiary amine and carbonate species as well as maximum possible concentration were determined. A new form of SPS with an amine : carbonate ratio significantly greater than unity has been identified. The N,N-dimethyl-n-alkylamine structure has been identified as important to the function of an SPS.

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