Abstract
AbstractX‐ray and neutron diffraction experiments on liquid bromobenzene are reported. After usually applied data reduction and evaluation the intramolecular contribution was separeted from the total intensity and the intramolecular structure in the liquid phase was determined. The combination of X‐ray and neutron differential cross sections permits an assignment of intermolecular distances to specific atom pairs. With this identification a two‐dimensional model is deduced. A quantitative calculation gives a refined model, reproducing both X‐ray and neutron data. The structure of the first coordination sphere is determined by strongly attractive forces between the bromine atom and the phenyl ring as well as a specific attraction of bromine atoms themselves leading to a characteristic distribution of distances.
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