Abstract

Procyanidins B2 and B1 were chemically oxidized to clarify the chemical changes in procyanidins upon oxidation. Four compounds were structurally determined and could be produced using different oxidation methods, including enzymatic oxidation with polyphenol oxidase. In the case of procyanidin B2, the different ratios of oxidized products formed in water compared with organic solvents are attributed to the procyanidin solvent-dependent conformational differences.

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