Abstract

Based on the heterometallic fragment {Li2Co2(Piv)6}, a new complex [(terpy)2Li2Co2(Piv)6] (1) was obtained, in which the terminal cobalt atoms coordinate the 2,2’:6’,2″-terpyridine (terpy) molecules. The metal core of the molecule is a Co—Li—Li—Co chain, the metal atoms in which are bonded between each other by the pairs of carboxylate bridges.

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